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2021

38. Sequential C-F bond functionalizations of trifluoroacetamides and acetates via spin-center shifts
Yu, Y.-J.(‡); Zhang, F.-L.(‡); Peng, T.-Y.; Wang, C.-L.; Cheng, J.; Chen, C.; Houk, K. N.*; Wang, Y.-F.*
(‡ Equal contribution)

Science 2021, 371, 1232-1240.
 

Science defluorination.png

2020

37. Lewis-base Boryl Radicals Enabled Borylation, Radical Catalysis, and Reduction Reactions
Jin, J.-K.; Xia, H.-M.; Zhang, F.-L.; Wang, Y.-F.*
Chin. J. Org. Chem. 2020, 40, 2185-2194.
(Account in Chinese)

Chin JOC account-Eng.png

36. Radical Hydroboration-Involved One-Pot Synthesis of Boron-Handled Glycol Derivatives
Zhuang, B.-Y.; Jin, J.-K.; Zhang, F.-L.*; Wang, Y.-F.*
Synlett. 2021, 32, 383-386.
(Cluster on ‘Radicals – by Young Chinese Organic Chemists’)

Zhuang Bi Yang work.png

35. New Radical Borylation Pathways for Organoboron Synthesis Enabled by Photoredox Catalysis
Qi, J.; Zhang, F.-L.; Jin, J.-K.; Zhao, Q.; Li, B.; Liu, L.-X.; Wang, Y.-F.*
Angew. Chem. Int. Ed. 2020, 59, 12876-12884.

Qi Jing Photocatalysis.png

34. Radical α-Addition Involved Electrooxidative [3+2] Annulation of Phenols and Electron-Deficient Alkenes

Zhao, Q.; Jin, J.-K.; Wang, J.; Zhang, F.-L.*; Wang, Y.-F.*

Chem. Sci. 2020, 11, 3909-3913.

Zhao electrochemistry.png

2019

33. Regioselective Radical Hydroboration of gem-Difluoroalkenes: Synthesis of α-Borylated Organofluorines

Jin, J.-K.; Zheng, W.-X.; Xia, H.-M.; Zhang, F.-L.*; Wang, Y.-F.*

Org. Lett. 2019, 21, 8414-8418.

difluoroboryl.png

32. Regioselective Radical Hydroboration of Electron-deficient Alkenes: Synthesis of α-Boryl Functionalized Molecules 

Huang, Y.-S; Wang, J.; Zheng, W.-X.; Zhang, F.-L.; Yu, Y.-J.; Zheng, M.; Zhou, X.*; Wang, Y.-F.*

Chem. Commun. 2019, 55, 11904-11907.

other electron deficient alkenes.png

31. NHC-Boryl Radical Catalysis for Cycloisomerization with C-C Triple Bond Reorganization

Xu, A.-Q.(‡); Zhang, F.-L.(‡); Ye, T.; Yu, Z.-X.*; Wang, Y.-F.*

(‡ Equal contribution)

CCS Chem. 2019, 1, 504-512.
radical catalysis.png

30. Lewis Base-Boryl Radical Enabled Giese Reaction and Barton Decarboxylation of NHPI Esters

Jin, J.-K; Zhang, F.-L.*; Wang, Y.-F.*

Acta Chim. Sinica DOI: 10.6023/A19050173.
Screen Shot 2019-09-07 at 14.16.33.png

29. Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules

Ren, S.-C.(‡); Zhang, F.-L.(‡); Xu, A.-Q.; Yang, Y.; Zheng, M.; Zhou, X.*; Fu, Y.*; Wang, Y.-F.*

(‡ Equal contribution)

Nat. Commun. 2019, 10, 1934. DOI: 10.1038/s41467-019-09825-3.
alfa-borylcarbonyl.png

2018

28. Synthesis of Diverse Boron-Handled N-Heterocycles via Radical Borylative Cyclization of N-Allylcyanamides

Jin, J.-K.; Zhang, F.-L; Zhao, Q.; Lu, J.-A.; Wang, Y.-F.*

Org. Lett2018, 20, 7558-7562. DOI: 10.1021/acs.orglett.8b03303.
cyanamide-TOC.png

27. Selective α‐Monomethylation by an Amine‒Borane/N,N‐Dimethylformamide System as the Methyl Source

Xia H.-M.(‡); Zhang, F.-L.(‡); Ye, T.; Wang, Y.-F.* (‡ Equal contribution)

Angew. Chem. Int. Ed. 2018, 57, 11770-11775. DOI : 10.1002/anie.201804794.
(Highlighted in Synfacts 2018, 14 (10), 1080. )

26. Radical Borylative Cyclization of 1,6-Dienes: Synthesis of Boron-Substituted Six-Membered Heterocycles and Carbocycles

Qing, J.(‡); Zhang, F.-L.(‡); Huang, Y.-S.; Xu, A.-Q; Ren, S.-C.; Yi, Z.-Y.; Wang, Y.-F.* (‡ Equal contribution)

Org. Lett. 2018, 20, 2360-2364. DOI: 10.1021/acs.orglett.8b00694

25. Lewis Base–Boryl Radicals Enabled the Desulfurizative Reduction and Annulation of Thioamides

Yu, Y.-J.(‡); Zhang, F.-L.(‡); Cheng, J.; Hei, J.-H.; Deng, W.-T.; Wang, Y.-F.* (‡ Equal contribution)

Org. Lett. 2018, 20, 24-27. DOI :10.1021/acs.orglett.7b03201

2017

24. Radical Borylation/Cyclization Cascade of 1,6-Enynes for the Synthesis of Boron-Handled Hetero- and Carbocycles
Ren, S.-C.(‡); Zhang, F.-L.(‡); Qi, J.; Huang, Y.-S.; Xu, A.-Q.; Yan, H.-Y.; Wang, Y.-F.* (‡ Equal contribution)
J. Am. Chem. Soc. 2017, 139, 6050-6053. DOI: 10.1021/jacs.7b01889
(Highlighted in Synfacts 2017, 13 (08), 804 )
(Highlighted in Chin. J. Org. Chem. 2017, 37, 1883.)

Before USTC

23. Linking of Alcohols with Vinyl Azides

Wang, Y.-F.; Hu, M.; Hayashi, H.; Xing, B.;* Chiba, S.*

Org. Lett. 2016, 18, 992-995.

 

22. Formal 4+2 -Annulation of Vinyl Azides with N-Unsaturated Aldimines

Zhu, X.; Wang, Y.-F.; Zhang, F.-L.; Chiba, S.*

​Chem. Asian J.  2014, 9, 2458-2462.

21. Amide Synthesis by Nucleophilic Attack of Vinyl Azides

Zhang, F.-L.; Wang, Y.-F.; Lonca, G. H.; Zhu, X.; Chiba, S.*

Angew. Chem. Int. Ed. 2014, 53, 4390-4394.

20. Synthesis of Polyfluoroalkyl Aza-Polycyclic Aromatic Hydrocarbons Enabled by Addition of Perfluoroalkyl Radicals onto Vinyl Azides

Wang, Y.-F.; Lonca, G. H.; Le Runigo, M.; Chiba, S.*

Org. Lett. 2014, 16, 4272-4275.

 

19. PhI(OAc)2-Mediated Radical Trifluoromethylation of Vinyl Azides with Me3SiCF3

Wang, Y.-F.; Lonca, G. H.; Chiba, S.*

Angew. Chem. Int. Ed. 2014, 53, 1067-1071.

18. Copper-Mediated Oxidative Transformation of N-Allyl Enamine Carboxylates toward Synthesis of Azaheterocycles

Toh, K. K.; Biswas, A.; Wang, Y.-F.; Tan, Y. Y.; Chiba, S.*

J. Am. Chem. Soc. 2014, 136, 6011-6020.

17. TEMPO-Mediated Aliphatic C-H Oxidation with Oximes and Hydrazones

Zhu, X.; Wang, Y.-F.; Ren, W.; Zhang, F.-L.; Chiba, S.*

Org. Lett. 2013, 15, 3214-3217.

16. Orthogonal aerobic conversion of N-benzyl amidoximes to 1,2,4-oxadiazoles or quinazolinones

Zhang, F.-L.; Wang, Y.-F.; Chiba, S.*

Org. Biomol. Chem. 2013, 11, 6003-6007.

 

15. Oxidative Radical Skeletal Rearrangement Induced by Molecular Oxygen: Synthesis of Quinazolinones

Wang, Y.-F.(‡); Zhang, F.-L.(‡); Chiba, S.* (‡ Equal contribution)

Org. Lett. 2013, 15, 2842-2845.

 

14. Copper-Catalyzed Aliphatic C-H Amination with an Amidine Moiety

Chen, H.; Sanjaya, S.; Wang, Y.-F.; Chiba, S.*

Org. Lett. 2013, 15, 212-215.

 

13. Copper-Catalyzed Aerobic 3+2 -Annulation of N-Alkenyl Amidines

Wang, Y.-F.(‡); Zhu, X.(‡); Chiba, S.* (‡ Equal contribution)

J. Am. Chem. Soc. 2012, 134, 3679-3682.

 

12. Copper-Catalyzed Aerobic Methyl/Methylene Oxygenation and C-H Formylation with a DABCO-DMSO System for the Synthesis of Carbonyl Indoles and Pyrroles

Wang, Y.-F.; Zhang, F.-L.; Chiba, S.*

Synthesis 2012, 44, 1526-1534.

 

11. Copper-Catalyzed Aerobic Aliphatic C-H Oxygenation Directed by an Amidine Moiety

Wang, Y.-F.(‡); Chen, H.(‡); Zhu, X.; Chiba, S.* (‡ Equal contribution)

J. Am. Chem. Soc. 2012, 134, 11980-11983.

 

10. Mn(III)-Mediated Formal 3+3 -Annulation of Vinyl Azides and Cyclopropanols: A Divergent Synthesis of Azaheterocycles

Wang, Y.-F.; Toh, K. K.; Ng, E. P. J.; Chiba, S.*

J. Am. Chem. Soc. 2011, 133, 6411-6421.

 

9. Synthesis of Isoquinolines from alpha-Aryl Vinyl Azides and Internal Alkynes by Rh-Cu Bimetallic Cooperation

Wang, Y.-F.; Toh, K. K.; Lee, J.-Y.; Chiba, S.*

Angew. Chem. Int. Ed. 2011, 50, 5927-5931.

8. Copper-Mediated Aerobic Synthesis of 3-Azabicyclo 3.1.0 hex-2-enes and 4-Carbonylpyrroles from N-Allyl/Propargyl Enamine Carboxylates

Toh, K. K. (‡); Wang, Y.-F.(‡); Ng, E. P. J.; Chiba, S.* (‡ Equal contribution)

J. Am. Chem. Soc. 2011, 133, 13942-13945.

7. Orthogonal synthesis of pyrroles and 1,2,3-triazoles from vinyl azides and 1,3-dicarbonyl compounds

Ng, E. P. J.; Wang, Y.-F.; Hui, B. W.-Q.; Lapointe, G.; Chiba, S.*

Tetrahedron 2011, 67, 7728-7737.

6. Annulation of Vinyl Azides and beta-Keto Acids for Synthesis of Pyrroles

Ng, E. P. J.; Wang, Y.-F.; Chiba, S.*

Synlett 2011, 783-786.

 

5. Isoquinolines from Aryl Ketone O-Acyloxime Derivatives and Internal Alkynes

Too, P. C.; Wang, Y.-F.; Chiba, S.*

Org. Lett. 2010, 12, 5688-5691.

4. Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo 3.3.1 non-2-en-1-ol Derivatives

Wang, Y.-F.; Chiba, S.*

J. Am. Chem. Soc. 2009, 131, 12570-12572.

 

3. A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, S.*; Xu, Y.-J.; Wang, Y.-F.

J. Am. Chem. Soc. 2009, 131, 12886-12887.

 

2. Mn(III)-Catalyzed Synthesis of Pyrroles from Vinyl Azides and 1,3-Dicarbonyl Compounds

Wang, Y.-F.; Toh, K. K.; Chiba, S.*; Narasaka, K.*

Org. Lett. 2008, 10, 5019-5022.

1. Synthesis of polysubstituted N-H pyrroles from vinyl azides and 1,3-dicarbonyl compounds

Chiba, S.*; Wang, Y.-F.; Lapointe, G.; Narasaka, K.*

Org. Lett. 2008, 10, 313-316.

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